Perfect to give charm to a room in your home. ![]() It's within a millisecond of the correct time, according to Untapped Cities tour guide Jeff Dobbins. 53.48 Delivery Time + Easy Return and Exchange + 24H Customer Support + Add a touch of vintage to your interior design with this station clock inspired by the famous New York Grand Central train station. ![]() Naval Observatory's atomic clock in Bethesda, Maryland. It takes about 20 minutes to get from the Grand Central Station clock tower down to where Mike Molway’s workers spent months with the pandemic-induced interruption on a repair. The Grand Central Station clock :, Grand Central Terminal HD wallpaper Tags: License: Original wallpaper info: PC(720P, 1080P, 2K, 4K, 5K): iMac: MacBook. Prepare for your upcoming travel with a little help from the MTA and Metro-North Railroad. The transit hub's famous clock in the center of the main concourse, which is estimated to be worth at least $10 million, is synced to the U.S. Grand Central Terminal is located at 89 E. 4.9 out of 5 stars - Shop Clock Concourse Grand Central Station New York Ceramic Ornament created by Everstock. With bold numbers, the black design features New York City Transit Authority and Grand Central Station Subway Line. There are plenty of ways to tell the time in Grand Central, besides using the mechanical clocks. alerting customers that the issues were resolved. ![]() The Metropolitan Transportation Authority alerted commuters Thursday morning that they are experiencing "technical difficulties with our mechanical clocks displaying the incorrect time." They advised travelers to listen for announcements or visit information booths for accurate train and track information.Īnother alert was sent by the MTA at 11:45 a.m. Watch Video: Video: Grand Central by the NumbersĬommuters looking to keep track of the time on their way to their destinations may not want to rely on Grand Central Terminal's clocks today.
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Nora had gotten the black death herself and was dying. He asks for her but the man he meets tells him he is too late. Eric leaves for the quarantined part of the city where Nora was helping the ill. This is highly contagious so he asks Eric to take her out of the situation and return her to him. She was instead helping people infected with the black plague. He wanted a certain woman at his bed, but she was too stubborn to be with him as he wanted. In 1665 Eric Northman was in London, doing a favor to king Charles II. Nora was born in Surrey, England in the 1640's of the Stuart Era. She was turned by Godric in 1665 when she became infected while trying to save a great portion of London from the devastating impact of the Black Plague. Nora had medium length brown hair, pale skin, blue eyes, and was of average height. When Lilith mercilessly destroyed Godric, Nora finally realized that Lilith was evil and cowered in fear of her. Nora was a devout religious vampire and when she was captured by the Authority and placed in her cell, the only thing she did is pray to Lilith. Like Godric, Eric and Pam, Nora spoke Swedish. However, she lacked self-discipline and, unlike her maker, seemed to have more regard for human life than some of her superiors. Though she cared for him deeply, and looked up to him, she dedicated her life to a higher purpose. ![]() Like many siblings, she and her " brother" enjoyed a fiery love/hate relationship. ![]() Nora was irreverent, intelligent, intimidating, cool under pressure and a very good liar. General procedure for the synthesis of indolizine compoundsĪ mixture of 0.1 mmol of the iminophosphorane intermediate (1-10) (Scheme 1 and Table 1) and 0.1 mmol of the corresponding 2,3-thiophenecarboxaldehyde in 2 mL of xylene was refluxed for 48 h. Chemical shifts for 13C NMR spectra are recorded in parts per million from tetramethyl silane using the central peak of CDCl 3 ( δ = 77.16 ppm) as the internal standard, all 13C NMR spectra were obtained with complete proton decoupling. The Hydrogen Nuclear Magnetic Resonance ( 1H NMR) and Carbon-13 Nuclear Magnetic Resonance ( 13C NMR) spectra were recorded on a Bruker 300 Megahertz (MHz) spectrometer operating at observation frequency of 300 MHz for 1H and 75 MHz for 13C, also was used a Varian 500MHz spectrometer operating at observation frequency of 500 MHz for 1H and 125 MHz for 13C chemical shifts for hydrogen are given in parts per million (ppm) relatives to tetramethyl silane (TMS) using the central peak of chloroform (CHCl 3) ( δ = 7.26 ppm) as internal standard. Melting points were determined with a Kofler Hot Stage Apparatus and were not corrected. Anhydrous solvents (ethanol, toluene) and reagents were used as from commercial bottles. This coupling is leading to the formation of the molecules derived from alkaloids core, specifically that of indolizines.Īll reactions were run under nitrogen atmosphere without moisture. In this context, we developed in this study a new strategy toward the title compounds using the iminophosphorane intermediates and their reaction with 2,3-thiophenedicarboxaldehyde. The indolizine containing molecules then became a challenging synthetic target and several strategic routes to build completely new structures in this family or simply to obtain known molecules in reduced number of steps or avoiding expensive reagents were proposed. Indolizine derivatives obtaining have become an important topic in organic synthesis. The indolizines nuclei are present for example in more complex molecules with potent analgesic, anti-inflammatory, antimicrobial, hypoglycemic, CNS depressor, antioxidant and anti- cancerogenic activities, inhibitors that modulate gene transcription. ![]() Indolizine synthesis is of growing interest in medicinal chemistry. In this context, synthesis of indolizines compounds has been reported using ingenious and sophisticated pyridine starting strategies. ![]() ![]() In particular, the development of new routes to achieve both, new and improved synthesis of these products, is in constant demand. Synthetic organic chemistry presents a significant and still growing number of reports focused on the synthesis of molecules with biological and pharmaceutical potential. ![]() New Orla Kiely Photo Books and Presentation Boxes.Save the Date for Orla Kiely's Past Season Sale.Orla Kiely for Target Travel Luggage and Accessories.Orla Kiely by Gaiam Yoga Items at Target.Use the Cross or Check marks in the top toolbar to select your answers in the list boxes. Start completing the fillable fields and carefully type in required information. Korjo Set Of 2 Leather Luggage Tags Black LT35. Hope this helps! Let me know which suitcase you end up with :) Quick steps to complete and e-sign Luggage tag template pdf online: Use Get Form or simply click on the template preview to open it in the editor. Go Travel Glo Luggage ID Tags (Twin Pack), Assorted Colours 568. In-store pickup, ready within 2 hours Same Day Delivery. The material seems prone to attracting dirt, but I think you can easily wipe it down and spot clean with soap and water. Luggage Tags : Sports Fan Shop Accessories & Jewelry Pickup. My only concern would be how dirty they would get. I used to have much cheaper suitcases that were not made as well, and they've held up very well after traveling several times (including two international trips), so I imagine the Orla Kiely ones will fare the same, if not better. Choose from Same Day Delivery, Drive Up or Order Pickup plus free shipping on. Now I know that's TOTALLY not the same as checking it in at the airport, so I honestly can't say how well it will hold up, but I can say that it seems like it has a solid construction and will hold up ok. Shop Target for easy spot luggage tags you will love at great low prices. I was somewhat rough with it myself dragging it up and down several flights of stairs, and aside from a few scratches on the wheels, it was still fine. I have only used it during a weekend getaway where my husband and I drove, so we were the only ones handling our suitcases. ![]() Hi! I honestly haven't used my 28" suitcase yet for traveling at the airport. Enter the variable value as the installation path of the JDK (appending the \bin sub-folder at the end of the path). In the System Properties window, select the Advanced tab, then Environment Variables. Open the Control Panel > System For those who want to finalize the furniture, folding desksable garden furniture having, a party or gardening, they can be relaxed and comfortable to rest. Find the perfect card table for your needs in various sizes. Buy Office Desks & Tables at discount prices. Make sure you have more than enough sitting space with folding tables from BJs Wholesale Club. Features: - Steady lock prevents falling - Vanilla white top, tough and stain-free - Corrosion-resistant, powder-coated high-grade steel, grey, fold-away legs - Heavy-duty blow-moulded polyethene tabletop (HDPE. With this increase, folding tables come in different sizes and shapes.įolding chairs and folding desksable furniture having, or a combination of both, can be used for a variety of purposes and at the same time. Browse & buy Maple Multi-functional Portable Plastic Folding Table, Off-White online at Dragon Mart. Commercial Grade 1.8M Plastic Folding Table - White. Folding Plastic Tables (1000+) Price when purchased online Walmarts pick 44.88 Mainstays 6 Foot Bi-Fold Plastic Folding Table, Black 1573 500+ bought since yesterday 49.47 Cosco 6 Foot Folding Table In White Speckle 2407 100+ bought since yesterday 37. ![]() ![]() With the folding furniture market value projected to grow at a CAGR of 4.3% from 2022 to 2030, it is expected to grow at a CAGR of 5.5% from 2030 to 2030, and is expected to grow at a CAGR of 5.6% from 2022 to 2030. ![]() They are also an great table for family gatherings, friends, and family. They are also useful for organizing parties and other events where on the go.Īn folding table or folding dining table can be used for outdoor events or picnics in the garden. Shop Folding Tables with confidence in JIJI.SG now and enjoy our 100 Days Hassle-Free Return Policy on selected products Enquires: salesjiji.sg Mon. Folding tables are a great way to bring style and class to your customers' events where they will be. ![]() The Fibonacci Sequence is a mathematical formula that is woven through the tapestry of life and forms patterns of spirals and vortexes that duplicate themselves everywhere in nature. The Fibonacci Sequence (Spiral) Golden Ratio: Phi 1.618 The powerful Vortexes and doorways into higher dimensions will allow us to speed up the spiritual manifestation process. We can create our own magick by using Sacred Geometry as a divination tool during our Ceremonial, Celestial, and Natural Practices. Sacred Geometry as a Divination Tool in Ceremonial, Celestial, and Natural Practices Sacred Geometry is a generative life force at work weaving together the fabric of the Universe and is inherent in all things, forms, patterns, and Fibonacci spirals. Sacred Geometry symbols are powerful images and shapes that are embedded in our DNA (twisted spiral and double helix), nature, galaxies, mandalas, pyramids, crystals, atoms, music, mystery, art, hieroglyphs, and so much more. Sacred Geometry is the Language of the Universe Sacred Geometry is not just an ancient science, but it is also a metaphysical language and energetic exchange of the different geometric shapes that govern the visible and invisible worlds. I love the power and the beauty behind Sacred Geometry as it is present everywhere, and it is also called the fingerprint of God as it shows up in all of creation. ![]() Used properly, however, close chords like this weigh heavy on the heart, and both composers deftly utilize that musical heft. The lower rumbling notes, rich as they are in overtones, sound goopy and indistinct, whereas the upper registers ring out more clearly. If you own a piano, play a minor triad using extremely low notes then, do the same in a higher register. ![]() In my early composition classes, I was taught that close chords in those deep ranges sound muddled and should be used with caution. Now I think of the sixth symphony's final movement, which features low cello and contrabass chords. I also tend to use a lot of chords with close intervals for tension building as well."Īh yes-another musical idea I associate with Tchaikovksy. In 'Gateless,' for example, the piece is in five but the bass line for the B section is in three, so it ends up feeling really tense. "One thing I like to do for building tension is to have rhythmic elements that fight a bit. It also tends to add extra tension!" That's not Korb's only tool for instilling anxiety, however. "I thought a hint of 'math' would be in keeping with the computer-ey terminology of the game. "I knew I wanted to play with some non-standard time signatures early on," he says. With this track in mind, I got in contact with Korb to probe his musical mind, and asked him about this choice. Korb, however, eases the tension by moving from five beats per measure to three during the track's refrain. Most music we listen to is organized into twos, threes, and fours 5/4 meter has a different kind of lilt, and can be vaguely unsettling to listen to. In the Transistor track called "In Circles," Korb also uses the same meter to evoke tension, albeit a different flavor of it. Tchaikovsky's sixth uses this time signature in its second movement, which sounds like an off-kilter waltz in which the dancers keep forgetting a step. Korb's work and Tchaikovsky's are miles apart in terms of harmonic and melodic content, but they have some commonalities that struck me, and one commonality in particular stood out: the use of 5/4 meter. My favorite Tchaikovsky work, however, is his sixth symphony, known as the Pathétique, and it was this symphony I thought of when I recently listened to Darren Korb's Transistor soundtrack. His music is known even outside the concertgoing public there's a good chance, for instance, that you have heard his music written for the ballets The Nutcracker and Swan Lake, and his 1812 Overture remains among the most popular works ever composed. Pyotr Ilyich Tchaikovsky was one of the greats. A good composer knows how to meet your musical expectations a great composer knows how to subvert them. ![]() She wears a light blue long-sleeved maxi dress, a black bib collar necklace, a black choker, black bracelets, and a light blue belt with small side pouches. She is widely acclaimed and admired throughout the cosmos which is why officials and celebrities attend her shows.ĭiva Plavalaguna has several tentacle-like appendages sticking out of her body. She was entrusted to keep the four elemental stones safe as they can help defeat the great evil that appears every five thousand years. Put in the necessary fillings for your conical head and tentacles by using these fiber fill material.Īccentuate your hips with this light blue skinny belt.Īttach a small belt pouch to each of your sides.įinalize your diva outfit by putting on this black nail polish before you showcase another of your galaxy-captivating performances.ĭiva Plavalaguna is the universally esteemed and treasured alien opera singer in the English-language French science fiction action movie Fifth Element. Use this baby blue polyester fabric to construct the tentacles for the sides of your head and for your back. Utilize this long deadlock cap to create your long conical head protrusion.ĭye and color your deadlock cap to make it sky blue. Wear this black chin strap to have Diva’s head strap and to allow attachment of your head appendages. Match the fashionable bib with these black choker and bracelets set. Put on this black bib collar necklace to approximate Diva’s neck-piece. While the Mad scene is far from the most traditional of operatic moments, it still retains the double aria structure of “slow” and “fast.” So too does Besson in this choice.Ĭheck it out to get an idea of how Besson works this scene, and by extension, his films as a whole.Diva Plavalaguna (Fifth Element) Costume for Cosplay & Halloween 2023īegin your elaborate costume by choosing this long light blue long-sleeved maxi dress. And yet, it keeps in line with the operatic structure of a bel canto opera, albeit with a pop twist. With its hyperactive coloratura leaps and almost impossible vocal lines, it is a stark contrast to Donizetti’s perfectly written lyrical style. And just when you are lulled into the world of opera, Diva Plavalaguna pulls out a dance number (called “The Diva Dance” in the soundtrack) by Éric Serra. We get everything you might expect from Lucia in this segment. ![]() In a four-plus minute single take, we see the soprano take on the beginning of the famous mad scene from “Lucia di Lammermoor.” It’s actually a rather famous story as Besson reportedly wanted to use the voice of Maria Callas for this segment, but due to sound issues, he opted for Inva Mula, who dubbed the singing section of it. And sure enough, when we first meet her, that is exactly what we get. The constant mentions of the opera singer soprano have us creating ideas that she might just be a relic of history in a rather bizarre world we’ve experienced. We’ve heard about her throughout the film as the key to having the element stones everyone is after. That is essentially what he does almost halfway through “The Fifth Element” when he finally introduces Diva Plavalaguna. And yet, the director strikes a balance with these two opposing sentiments so that we never doubt his presence as a potent antagonist the hero Leon. In fact, you start to wonder just how far Besson might push that comic aspect at times. Meanwhile, Norman is a murderous villain who still gives us a few laughs due to his pathetic nature. Besson pushes the subject a bit to shock the audience, but never far enough that we stop believing the character altogether. ![]() We sympathize with Mathilda’s plight and yet she scares us out a bit with her subdued infatuation with Leon. One of my favorite examples has to be in “Leon the Professional” where its characters, particularly the precocious 12-year-old Mathilda Lando and Norman Stansfield, are both familiar and off-putting at the same time. It’s an odd balance that he strikes so beautifully in all his work. We always feel that his most outrageous moments are not so outlandish. And yet we always feel that he’s retaining a certain level of conservative cinematic structure in his movies. Just when you think you might have his intentions pinned down because he’s given you something rather traditional, he throws a curveball that turns expectations on their head. The director, whether working on an animated film, a suspense thriller, or a sci-fi classic, always manages to keep the viewer shocked and comfortable at the same time. Luc Besson’s films are strange and yet familiar. This week’s installment features Luc Besson’s “ The Fifth Element.” We will select a section or a film in its entirety, highlighting the impact that utilizing the operatic form or sections from an opera can alter our perception of a film that we are viewing. “Opera Meets Film” is a feature dedicated to exploring the way that opera has been employed in cinema. En route, Brewer Capri Marina (can accommodate up to 150 feet) offers a great stop-over in beautiful Port Washington on the Long Island Sound. Within easy access from the cacophony of Manhattan are the world-class beaches, seaside restaurants and upscale atmosphere of Long Island's Hamptons. ![]() Across the Hudson River in Jersey City is Liberty Landing Marina, accommodating vessels up to 200 feet (12-foot dock depth), and Newport Yacht Club and Marina which offers 12 berths for vessels up to 180 feet (10-foot dock depth). The variation in dining is staggering, and over the last few years the restaurant scene has undergone a seismic shift as Old World giants give way to more accessible food in casual atmospheres.Dockage is available in Manhattan at MarineMax at Chelsea Pier for vessels up to 320 feet (18-foot dock depth) or North Cove Marina, offering eight megayacht berths for vessels up to 175 feet (18-foot dock depth). Any description will be passé by the next day in this dynamic environment, especially when it comes to restaurants. It's anything and everything and no specific thing. The pages of a thesaurus would be worn ragged finding enough adjectives to describe New York City. Enjoy cruising the Northeast this summer! New York, N.Y. From New York City to Bar Harbor, enjoy shopping, dining, sightseeing and breezy nights along the way.We put together an itinerary of destinations, with many top-notch marinas and facilities that can accommodate large yachts (more than 80 feet). The diversity of culture and terrain, the changing seasons, the world's most dynamic cities surrounded by small villages striking in their simplicity all invite deeper exploration.Yachts escaping the southern heat, port-hop during the summer months between popular tourist spots and secluded anchorages along the coastline. NEW YORK CITY bagels, New England clam bake, Boston cream pies, Maine lobster rolls, maple syrup, johnnycakes, baked beans, seafood chowder, coffee milk, whoopie pies and blueberry everything who needs more reasons to spend time in the Northeast?Aside from the amazing cuisine and the obvious historical significance, there are many more incentives to visit. Says Wagner, "We are looking forward to plans which will expand the dockage and amenities at National Harbor Marina to accommodate more large vessels and superyachts, making this a world-class marina destination." This fall, be sure to put National Harbor Marina on your list. Slated to open in late 2016, the new 308-room MGM National Harbor resort will take things to the next level, with a dynamic casino, a world-class spa and salon, an entertainment theater, high-end retailers, two nightlife venues and numerous restaurants. The shopping is also excellent, with luxury-brand outposts and funky specialty shops - there is truly something for everyone. National Harbor includes an eclectic mix of eateries, from seafood spots and steakhouses to ice cream and coffee shops. There are countless walking and biking trails that wind across the Woodrow Wilson Bridge into Old Town Alexandria, and on-site water taxis can shuttle you to Alexandria, Georgetown, the National Mall and even the Nationals' baseball stadium. Other popular events include the pet-friendly Yappy Hour, morning yoga, a Sunday morning farmers market and sunset concerts. In the mood for a movie? During the summer, National Harbor plays date-night movies on Thursdays and family flicks on Fridays. For those who enjoy water activities, rent a kayak, paddleboard or pedal boat and take in National Harbor from the water. There's certainly no opportunity to get bored. "With its numerous attractions and proximity to the nation's capital, National Harbor has become even more appealing to the boating community not only from the immediate area, but throughout the entire East Coast," says Bruce Wagner, Vice President of Coastal Properties. ![]() On-site amenities include a marina-exclusive bathhouse, laundry facility/lounge, WiFi, a fuel dock with gasoline and high-speed diesel pumps, 24-hour security with locked gates and concierge services. The marina can accommodate vessels up to 250 feet with a dock depth of 9 feet. The 76-slip National Harbor Marina is managed by Island Global Yachting. And because of the repeal of the Maryland law requiring any vessel larger than 79 feet to have a licensed bay pilot aboard, superyachts can now navigate up the Potomac River pilot-free. ![]() ![]() The marina is part of the 350-acre National Harbor property, which has more than 150 diverse shops and boutiques, 30 dining locations and an iconic Ferris wheel, the Capital Wheel. NATIONAL HARBOR MARINA is located five miles south of Washington D.C., along the banks of the Potomac River. |
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